2016 |
|
74.
|
Hot Paper |
73.
|
Li, Gang; Yoon, Ki-young; Zhong, Xinjue; Zhu, Xiao-Yang;* Dong, Guangbin.* "Efficient Bottom-Up Preparation of Graphene Nanoribbons via Mild Suzuki-Miyaura Polymerization of Simple Triaryl Monomers." Chem. Eur. J., 2016, DOI: 10.1002/chem.201602007. [doi] |
72. |
Hayes, Colin; Chen, Peng-hao; Thedford, Paxton; Ellison, Christopher; Dong, Guangbin; Willson, Grant.* "Effect of Ring Functionalization on the Reaction Temperature of Benzocyclobutene Thermoset Polymers." Marcomolecules, 2016, ASAP. [doi] |
71. |
Ren, Zhi; Dong, Guangbin.* "Direct Observation of C−H Cyclopalladation at Tertiary Positions Enabled by an Exo-Directing Group". Organometallics, 2016, 35, 1057. [doi] |
70. |
Huang, Zhongxing; Wang, Chengpeng; Dong, Guangbin.* "A Hydrazone-Based exo-Directing Group Strategy for β-C–H Oxidation of Aliphatic Amines". Angew. Chem., Int. Ed. 2016, 55, 5299. [doi] |
69. |
Lim, Hee Nam; Dong, Guangbin.* "Catalytic Cage Formation via Controlled Dimerization of Norbornadienes: An Entry to Functionalized HCTDs (Heptacyclo[6.6.0.02,6.03,13.04,11.05,9.010,14]tetradecanes)". Org. Lett. 2016,18, 1104. [doi] |
68. |
Xu, Yan; Su, Tianshun; Huang, Zhongxing; Dong, Guangbin.* "Practical Direct α-Arylation of Cyclopentanones by Palladium/Enamine Cooperative Catalysis". Angew. Chem., Int. Ed. 2016, 55, 2559. [doi] |
67. |
Zeng, Rong; Chen, Peng-hao; Dong, Guangbin.* "Efficient Benzimidazolidinone Synthesis via Rhodium-Catalyzed Double-Decarbonylative C-C Activation/Cycloaddition between Isatins and Isocyanates". ACS Catal. 2016, 6, 969-973. [doi] |
66. |
Deng, Lin; Xu, Tao; Li, Hongbo; Dong, Guangbin.* "Enantioselective Rh-catalyzed Carboacylation of C=N Bonds via C−C Activation of Benzocyclobutenones". J. Am. Chem. Soc. 2016, 138, 369-374. [doi] *Highlighted by Synfacts 2016; 12(3): 0288. |
65. |
Invited Review: |
2015 |
|
64. |
Mo, Fanyang; Lim, Hee Nam; Dong, Guangbin.* "Bi-functional Ligand-assisted Catalytic Ketone α-Alkenylation with Internal Alkynes: Controlled Synthesis of Enones and Mechanistic Studies". J. Am. Chem. Soc. 2015, 137, 15518-15527. [doi] |
63. |
Whittaker, R. E.; Dong, Guangbin.* "Controlled Rh-Catalyzed Mono- and Double-decarbonylation of Alkynyl α-Diones to Form Conjugated Ynones and Disubstituted Alkynes". Org. Lett. 2015, 17, 5504-5507. [doi] |
62. |
Lim, Hee Nam; Dong, Guangbin.* "Catalytic Intramolecular Ketone Alkylation with Olefins by Dual Activation". Angew. Chem., Int. Ed. 2015, 54, 15294-15298. [doi] |
61. |
Zhou, Xuan; Dong, Guangbin.* "(4+1) vs (4+2): Catalytic Intramolecular Coupling between Cyclobutanones and Trisubstituted Allenes via C−C Activation". J. Am. Chem. Soc. 2015, 137, 13715-13721. [doi] *Highlighted by Synfacts 2016; 12(1): 0041. |
60. |
Dong, Zhe;‡ Wang, Jianchun;‡ Ren, Zhi; Dong, Guangbin.* "Ortho C−H Acylation of Aryl Iodides by Palladium/Norbornene Catalysis". Angew. Chem., Int. Ed. 2015, 54, 12664-12668. [doi] |
59. |
Thompson, Samuel J.; Thach, Danny Q.; Dong, Guangbin.* "Cyclic Ether Synthesis via Palladium-Catalyzed Directed De-hydrogenative Annulation at Unactivated Terminal Positions". J. Am. Chem. Soc. 2015, 137, 11586-11589. [doi] |
58. |
Xu, Yan;‡ Yan, Guobing;‡ Ren, Zhi; Dong, Guangbin.* "Diverse sp3 C−H Functionalization Through Alcohol β-Sulfonyloxylation". Nature Chem. 2015, 7, 829-834. [doi] Highlighted by the Japanese Language Chem-Station! [link] 2nd Most Read Paper in Previous 15 Days (September 7th, 2015)! [link] |
57. |
Huang, Zhongxing; Sam, Quynh P.; Dong, Guangbin.* "Palladium-Catalyzed Direct β-Arylation of Ketones with Diaryliodonium Salts: a Stoichiometric Heavy Metal-Free and User-Friendly Approach". Chem. Sci. 2015, 6, 5491-5498. [doi] |
56. |
Huang, Zhongxing; Lim, Hee Nam; Mo, Fanyang; Young, Michael C.; Dong, Guangbin.* "Transition Metal-Catalyzed Ketone-Directed or Mediated C−H Functionalization". Chem. Soc. Rev. 2015, 44, 7764. [doi] |
55. |
Chen, Peng-hao; Sieber, Joshua; Senanyake, Chris. H.; Dong, Guangbin.* "Rh-Catalyzed Reagent-Free Ring Expansion of Cyclobutenones and Benzocyclobutenones". Chem. Sci. 2015, 6, 5440-5445. [doi] |
54. |
Lu, Gang; Fang, Cheng, Xu, Tao; Dong, Guangbin; Liu, Peng.* "Computational Study of Rh-Catalyzed Carboacylation of Olefins: Ligand-Promoted Rhodacycle Isomerization Enables Regioselective C-C Bond Functionalization of Benzocyclobutenones". J. Am. Chem. Soc. 2015, 137, 8274-8283. [doi] |
53. |
Ren, Zhi; Schulz, Jonathan E.; Dong, Guangbin.* "Catalytic Ortho-Acetoxylation of Masked Benzyl Alcohols via an Exo-Directing Mode". Org. Lett. 2015, 17, 2696-2699. [doi] |
52. |
Zhe, Dong; Wang, Jianchun; Dong, Guangbin.* "Simple Amine-Directed meta-Selective C−H Arylation via Pd/Norbornene Catalysis". J. Am. Chem. Soc. 2015, 137, 5887-5890. [doi] Highlighted by the Organic Chemistry Portal! [link] *Highlighted by JOC 2016; 81(2): 343. |
51. |
Dermenci, Alpay;‡ Whittaker, Rachel E.;‡ Gao, Yang; Cruz, Faben; Yu, Zhixiang;* Dong, Guangbin.* "Rh-Catalyzed Decarbonylation of Conjugated Ynones via Carbon−Alkyne Bond Activation: Reaction Scope and Mechanistic Exploration via DFT Calculations". Chem. Sci. 2015, 6, 3201-3210. [doi] Top 25 most downloaded in Q2 2015! [link] |
50. |
Invited article for Prof. Yoshiaki Nakao Tetrahedron Young Investigator Award |
49. |
Zeng, Rong; Dong, Guangbin.* "Rh-Catalyzed Decarbonylative Cycloaddition with Alkynes via C−C Activation of Isatins". J. Am. Chem. Soc. 2015, 137, 1408–1411. [doi] |
2014 |
|
48. |
Book Volume With contributions by the groups of Prof. William D. Jones, Prof. Yoshiaki Nakao, Prof. Chul-Ho Jun, Prof. Christopher J. Douglas, Prof. Jason S. Kingsbury, Prof. Nicolai Cramer and Prof. Zhi-Xiang Yu. |
47. |
Invited review |
46. |
VIP in Angewandte Chemie |
45. |
Xu, Tao; Dong, Guangbin.* "Coupling of Sterically Hindered Trisubstituted Olefins and Benzocyclobutenones by C–C Activation: Total Synthesis and Structural Revision of Cycloinumakiol". Angew. Chem., Int. Ed. 2014, 53, 10733–10736. [doi] |
44. |
Thompson, S. John; Dong, Guangbin.* "Alkylation of Rhodium Porphyrins Using Ammonium and Quinolinium Salts". Organometallics 2014, 33, 3757–3767. [doi] |
43. |
Ko, Haye Min; Dong, Guangbin.* “Cooperative activation of cyclobutanones and olefins leads to bridged ring systems by a catalytic [4 + 2] coupling”. Nature Chemistry 2014, 6, 739–744. [doi] |
42. |
Mo, Fanyang; Dong, Guangbin.* "Regioselective ketone α-alkylation with simple olefins via dual activation". Science 2014, 345, 68–72. [doi] *Highlighted by Chemical & Engineering News 2014, 92(27), 6. Ketones Couple With Olefins In Alkylation Advance |
41. |
Invited article for 2014 Emerging Investigators issue: |
40. |
Invited article for Prof. Sarah Reisman Tetrahedron Young Investigator Award: |
39.
|
Invited Review: Top 3 most-read articles in Aug. 2013. [link] |
38. |
Invited Review: |
37. |
Xu, Tao; Savage, Nikolas A.; Dong, Guangbin.* "Rhodium(I)-Catalyzed Decarbonylative Spirocyclization through C-C Bond Cleavage of Benzocyclobutenones: An Efficient Approach to Functionalized Spirocycles". Angew. Chem., Int. Ed. 2014, 53, 1891–1895. [doi] |
36. |
VIP in Angewandte Chemie *Highlighted by Synfacts 2014; 10(5): 0469. |
35. |
Pan, Ming; Gong, Jinlong; Dong, Guangbin; Mullins, C. Buddie.* "Model Studies with Gold: A Versatile Oxidation and Hydrogenation Catalyst". Acc. Chem. Res. 2014, 47, 750–760. [doi] |
2013 |
|
34.
|
Dong, Zhe; Dong, Guangbin.* "Ortho vs Ipso: Site-Selective Pd and Norbornene-Catalyzed Arene C-H Amination Using Aryl Halides". J. Am. Chem. Soc. 2013, 135, 18350–18353. [doi] Most read articles in Dec. 2013. *Highlighted by Org. Process Res. Dev. 2014, 18, 362.. *Highlighted by Organic Chemistry Portal 2014 June16. |
33. |
Huang, Zhongxing; Dong, Guangbin.* "Catalytic Direct β-Arylation of Simple Ketones with Aryl Iodides". J. Am. Chem. Soc. 2013, 135, 17747-17750. [doi] Top 1 most read articles in Dec. 2013. *Highlighted by Synform 2014-03. *Highlighted by Chemical & Engineering News 2013, 91, 28. *Highlighted by Organic Chemistry Portal 2014 Sep08. Metal Duo Makes β-Aryl Ketones The carbons immediately adjacent to a carbonyl group are usually straightforward places to form new carbon-carbon bonds. Just use a strong base, or a carefully designed catalyst, and that α-carbon is good to go. The next carbon over, the β-carbon, is not so amenable to change, however. Traditionally, β-substituted carbonyls require multiple steps to prepare. Because that β-motif is common in insecticides and drug candidates, chemists are keen to simplify the process. They've developed a handful of β-functionalization reactions, but none is generally applicable yet. Now, graduate student Zhongxing Huang and assistant professor Guangbin Dong of the University of Texas, Austin, have added to the toolbox with a reaction that inserts aromatic rings at the β-position of simple ketones (J. Am. Chem. Soc. 2013, DOI: 10.1021/ja410389a). The palladium-catalyzed process uses readily available aryl iodides and bromides as the substrates. A silver salt regenerates the active catalyst. Dong cautions that the reaction is still in its infancy. He'd like to figure out the reaction mechanism and replace the silver reagent with something less expensive. UT Austin is pursuing a provisional patent on the chemistry. |
32. |
Invited Review: |
31. |
Invited Review: *Awarded the 2013 best paper award by Science China Chemistry. |
30. |
Dermenci, Alpay; Whittaker, Rachel; Dong, Guangbin.* "Rh(I)-Catalyzed Decarbonylation of Diynones via C-C Activation: Orthogonal Synthesis of Conjugated-Diynes". Org. Lett. 2013, 15, 2242. [doi] *Highlighted by SYNFACTS issue 07/13. |
29.
|
Invited Highlights: |
2012 |
|
28.
|
Xu, Tao; Ko, Haye Min; Savage, Nikolas; Dong, Guangbin.* " Highly Enantioselective Rh-Catalyzed Carboacylation of Olefins: Efficient Syntheses of Chiral Poly-Fused Rings ". J. Am. Chem. Soc. 2012, 134, 20005. [doi] |
27. |
Mo, Fanyang; Trzepkowski, Louis J.; Dong, Guangbin.* "Synthesis of ortho-Acylphenols via Pd-Catalyzed Ketone-Directed Hydroxylation of Arenes". Angew. Chem., Int. Ed. 2012, 51, 13075. [doi] |
26. |
Ren, Zhi;‡ Mo, Fanyang;‡ Dong, Guangbin.* "Catalytic Functionalization of Unactivated sp3 C–H Bonds via exo-Directing Groups: Synthesis of Chemically Differentiated 1,2-Diols". J. Am. Chem. Soc. 2012, 134, 16991. [doi] The third most read JACS article in Nov 2012. *Highlighted by Nature Chemistry 2014, 6, 94-96. |
25. |
Pan, Ming; Brush, Adrian; Dong, Guangbin; Mullins, C. Buddie.* "Tunable Ether Production via Coupling of Aldehydes or Aldehyde/Alcohol over Hydrogen-Modified Gold Catalysts at Low Temperatures" The Journal of Physical Chemistry Letters, 2012, 3, 2512. [doi] |
24. |
Wang, Zhiqian; Reinus, Brandon; Dong, Guangbin.* "Catalytic Intermolecular C-Alkylation of 1,2-Diketones with Simple Olefins: A Recyclable Directing Group Strategy". J. Am. Chem. Soc. 2012, 134, 13954. [doi] |
23. |
Teo. Peili; Wickens, Zachary K.; Dong, Guangbin; Grubbs, Robert H.* "Efficient and Highly Aldehyde Selective Wacker Oxidation." Organic Letters, 2012, 14, 3237. [doi] |
22. |
Xu, Tao; Dong, Guangbin.* "Rh-Catalyzed Regioselective Carboacylation of Olefins: A C-C Activation Approach to Access Fused-Ring Systems." Angew. Chem., Int. Ed. 2012, 51, 7567. [doi] *Highlighted by Chemical & Engineering News, 90(27), July 02, 2012 Cut-And-Sew Route Makes Fused Rings. |
21. |
Trost, Barry M.*; Osipov, Maksim.; Dong , Guangbin. "Palladium-Catalyzed Asymmetric Allylic Alkylation of Electron-Deficient Pyrroles with Meso Electrophiles" Organic Letters, 2012, 14, 2254. [doi] |
2011 |
|
20. |
Dong, Guangbin; Teo, Peili; Wickens, Zachary, K.; Grubbs, Robert H.* “Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration-like Process via Triple Relay Catalysis” Science, 2011, 333(6049), 1609-1612. [doi] *Highlighted by Chemical & Engineering News, 89(38), September 19, 2011 *Highlighted by CHEMCATCHEM, DOI: 10.1002/cctc.201100407 The search for anti-Markovnikov: The catalytic anti-Markovnikov hydration of terminal alkenes: how can it be done? Robert H. Grubbs et al. have partially answered this question. To design multiple coupled catalytic cycles is a complex endeavor, which is discussed here in the context of recent results. Increasingly mild coupled redox reactions look to help solve this intrinsic problem. |
19. |
Trost, Barry M.;* Ngai, Ming-Yu; Dong, Guangbin “Ligand-accelerated enantioselective propargylation of aldehydes via allenylzinc reagents” Organic Letters, 2011, 13, 1900-1903. [doi] |
18. |
Trost, Barry M.;* Frontier, Alison J.; Thiel, Oliver R.; Yang, Hanbiao; Dong, Guangbin “Total Syntheses of Bryostatins. Methods Developments: Atom-Economic and Stereoselective Synthesis of C-ring Subunit” Chemistry - A European Journal, 2011, 17, 9762-9776. [doi] |
17. |
Trost, Barry M.;* Yang, Hanbiao; Brindle, Cheyenne S.; Dong, Guangbin “Atom-Economic and Stereoselective Syntheses of the Ring A and B Subunits of the Bryostatins” Chemistry - A European Journal, 2011, 17, 9777-9788. [doi |
16. |
Trost, Barry M.;* Yang, Hanbiao, Dong, Guangbin “Total Syntheses of Bryostatins. Syntheses of Two Ring-Expanded Bryostatin Analogues and Development of a New-Generation Strategy to Access the C7-C27 Fragment” Chemistry - A European Journal, 2011, 17, 9789-9805. [doi] |
2010 |
|
15. |
Trost, Barry M.;* Dong, Guangbin “Total Synthesis of Bryostatin 16 using a Pd-Catalyzed Diyne-coupling as Macrocyclization Method and Synthesis of C20-epi-Bryostatin 7 as a Potent Anticancer Agent” Journal of the American Chemical Society, 2010, 132, 16403–16416. [doi] |
14. |
Dong, Guangbin* “A Historical Story on the Synthesis of Agelastatin” Pure and Applied Chemistry, 2010, 82, 2231-2246 (2010 IUPAC Prize for Young Chemists, invited review). [doi] |
13. |
Trost, Barry M.;* Osipov, Maksim; Dong, Guangbin “Palladium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Vinyl Aziridines with Nitrogen Heterocycles: Rapid Access to Biologically Active Pyrroles and Indoles” Journal of the American Chemical Society, 2010, 132, 15800–15807. [doi] |
12. |
Trost, Barry M.;* Osipov, Maksim; Dong, Guangbin “A Concise Enantioselective Synthesis of (–)- Ranirestat.” Organic Letters, 2010, 12, 1276-1279. [doi] |
11. |
Trost, Barry M.;* Dong, Guangbin; Vance, Jennifer A. “Cyclic 1,2-Diketones as Core Building Blocks: A Strategy for the Total Synthesis of (–)-Terpestacin.” Chemistry - A European Journal, 2010, 16, 6265-6277. [doi] |
2009 |
|
10. |
Trost, Barry M.;* Dong, Guangbin “A Stereodivergent Strategy to Both Product Enantiomers from the Same Enantiomer of A Stereoinducing Catalyst: Agelastatin A.” Chemistry - A European Journal, 2009, 15, 6910-6919. [doi] |
2008 |
|
9. |
Trost, Barry M.;* Dong, Guangbin “Total Synthesis of Bryostatin 16 Using Atom Economical and Chemoselective Approaches.” Nature, 2008, 456, 485-488. [doi] Highlighted by Angewandte Chemie International Edition (2009, 48, 3221-3223) [doi], Chemical and Engineering News (2008, 8, 11) [doi], Chemistry World of Royal Chemical Society (2008, 27 November) and Nature (2008, 456, 451-453.) [doi] |
8. |
Dong, Guangbin* “Hosomi–Sakurai Reaction” Vol. 3, 139-180; Modern Organic Reactions, Hu, Yuefei; Lin, Guoqiang Eds, Chemical Industry Press: Beijing, 2008. |
2007 |
|
7. |
Trost, Barry M.;* Dong, Guangbin “Asymmetric Annulation toward Pyrrolo-piperazinones. Concise Enantioselective Syntheses of Pyrrole Alkaloid Natural Products.” Organic Letters, 2007, 9, 2357-2359. [doi] |
6. |
Trost, Barry M.;* Dong, Guangbin; Vance, Jennifer A. “A Diosphenol-Based Strategy for the Total Synthesis of (–)-Terpestacin.” Journal of the American Chemical Society, 2007, 129, 4540-4541. [doi] |
2006 |
|
5. |
Trost, Barry M.;* Dong, Guangbin “New Class of Nucleophiles for Palladium-Catalyzed Asymmetric Allylic Alkylation. Total Synthesis of Agelastatin A.” Journal of the American Chemical Society, 2006, 128, 6054-6055. [doi] |
Before 2005 |
|
4. |
Tang, Yefeng; Deng, Lujiang; Zhang, Yandong; Dong, Guangbin; Chen, Jiahua;* Yang, Zhen* “Thioureas as Ligands in the Pd-Catalyzed Intramolecular Pauson-Khand Reaction.” Organic Letters, 2005, 7, 1657-1659. [doi] |
3. |
Tang, Yefeng; Deng, Lujiang; Zhang, Yandong; Dong, Guangbin; Chen, Jiahua;* Yang, Zhen* “Tetramethyl Thiourea/Co2(CO)8-Catalyzed Pauson-Khand Reaction under Balloon Pressure of CO.” Organic Letters, 2005, 7, 593-595. [doi] |
2. |
Dai, Mingji; Liang, Bo; Wang, Cuihua; You, Zejin; Xiang, Jing; Dong, Guangbin; Chen, Jiahua;* Yang, Zhen* “A Novel Thiourea Ligand Applied in the Pd-Catalyzed Heck, Suzuki and Suzuki Carbonylative Reactions.” Advanced Synthesis & Catalysis 2004, 346, 1669-1673. [doi] |
1. |
Dai, Mingji; Wang, Cuihua; Dong, Guangbin; Xiang, Jing; Luo, Tuoping; Liang, Bo; Chen, Jiahua;* Yang, Zhen* “Development of Thiourea-based Ligands for the Pd-Catalyzed Bis(methoxy -carbonylation) of Terminal Olefins.” European Journal of Organic Chemistry, 2003, 22, 4346-4348. [doi] |
SELECTED PRESENTATIONS
- Dong, Guangbin; Wickens, Zachary, Teo, Peili; K.; Grubbs, Robert H. “Direct Synthesis of Primary Alcohols from Non-activated Terminal Olefins: A Catalytic Anti-Markovnikov Hydration-like Process Using a Triple Relay Catalysis System” 42th National Organic Symposium, Princeton, NJ, June 5-9, 2011.
- Dong, Guangbin; Trost, Barry M. “Synthetic Efficiency: Using Atom-Economical and Chemoselective Approaches towards Total Syntheses of Agelas Alkaloids, Terpestacin and Bryostatins.” Gordon Research Conferences: Natural Products, Tilton, NH, July 25-30, 2010.
- Dong, Guangbin; Trost, Barry M. “Total Synthesis of Bryostatin.” Division of Organic Chemistry, 238th American Chemical Society National Meeting, Washington, DC, August 16-20, 2009 (oral talk).
- Dong, Guangbin; Trost, Barry M. “Synthetic Efficiency: Using Atom-Economical and Chemoselective Approaches towards Total Syntheses of Agelas Alkaloids, Terpestacin and Bryostatins.” 41th National Organic Symposium, Boulder, CO, June 7-11, 2009.
- Dong, Guangbin; Trost, Barry M. “Palladium and Ruthenium Catalysis: Enantioselective Total Syntheses of Pyrrole Alkaloid Natural Products, (–)-Terpestacin, and Total Synthesis of Bryostatin 16” Division of Organic Chemistry, 236th American Chemical Society National Meeting, Philadelphia, PA, August 17-21, 2008.
- Dong, Guangbin; Trost, Barry M. Vance, Jennifer A. “A Diosphenol-Based Strategy for the Total Synthesis of (–)-Terpestacin.” Division of Organic Chemistry, 234th American Chemical Society National Meeting, Boston, MA, August 19-23, 2007 (oral talk).
- Dong, Guangbin; Trost, Barry M. “Palladium and Ruthenium Catalysis: Enantioselective Total Syntheses of Pyrrole Alkaloid Natural Products, (–)-Terpestacin, and Progress Towards the Total Synthesis of Bryostatin” Johnson Symposium: Poster Session, Stanford University, Stanford, CA, 2007.